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Ethylidene diacetate : ウィキペディア英語版 | Ethylidene diacetate
|Section2= |Section7= }} Ethylidene diacetate is an organic compound with the formula (CH3CO2)2CHCH3. A colorless solid, it once served as a precursor to vinyl acetate. ==Preparation== A major industrial route involves the reaction of acetaldehyde and acetic anhydride in the presence of a ferric chloride catalyst:〔G. Roscher "Vinyl Esters" in ''Ullmann's Encyclopedia of Chemical Technology'', 2007 John Wiley & Sons: New York. 〕 :CH3CHO + (CH3CO)2O → (CH3CO2)2CHCH3 It can be converted to the valuable monomer vinyl acetate by thermal elimination of acetic acid: :(CH3CO2)2CHCH3 → CH3CO2CH=CH2 + CH3CO2H
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